Spiro, Ansa ve Bino Sikloklorotrifosfazen Türevlerinin Sentezleri ve Spectroskopik Araştırmaları.

Authors : Sedat Ture

Pages : 113-120

Doi:10.16984/saufbed.95105

View : 22 | Download : 15

Publication Date : 2011-12-01

Article Type : Research Paper

Abstract :The reactions of hexachlorocyclotriphosphazatriene, N3P3Cl6 insert ignore into journalissuearticles values(1); with 2,2-dimethylpropane-1,3-diol yield 9 new cyclophosphazene derivatives. One monospiro, N3P3Cl4[insert ignore into journalissuearticles values(OCH2);2-CMe2], dispiro, N3P3Cl2[insert ignore into journalissuearticles values(OCH2);2-CMe2]2 and tris-spiro N3P3[insert ignore into journalissuearticles values(OCH2);2-CMe2]3 derivatives. An ansa, N3P3Cl4[insert ignore into journalissuearticles values(OCH2);2-CMe2], and a spiro-ansa, N3P3Cl2[insert ignore into journalissuearticles values(OCH2);2-CMe2]2 isomers. One dangling, N3P3Cl5[insert ignore into journalissuearticles values(OCH2);2-CMe2OH], one singly-bridged, N3P3Cl5[insert ignore into journalissuearticles values(OCH2);2-CMe2] N3P3Cl5, one doubly-bridged, N3P3Cl4[insert ignore into journalissuearticles values(OCH2);2-CMe2]2N3P3Cl4, and one triple-bridged compounds, N3P3Cl3[insert ignore into journalissuearticles values(OCH2);2-CMe2]2N3P3Cl3 were also isolated. Product types and relative yields were compared with those arising from propane-1,3-diol. The yields of the spiro, ansa and the bridged products from the reactions of the dimethylpropane-diol system seem to be considerably enhanced relative to those of its unmethylated analogue. The structures of the compounds were determined by using the data obtained from 31P, 1H and 13C N.M.R.
Keywords : Sikloklorotrifosfazatrien, bis 2 hidroksietil, eter, spiro bileşikleri, ansa bileşikleri, dangling türevi, bino bileşikleri, N M R verileri