Synthesis, Characterization and Photocatalytic Properties of Non-peripherally 3- (pyridin-4-yl) propane-1-oxy Groups Substituted Cu (II) Phthalocyanine and Water Soluble Derivative

Authors : Ece Tuğba SAKA

Pages : 1029-1039

Doi:10.16984/saufenbilder.630325

View : 27 | Download : 10

Publication Date : 2020-10-01

Article Type : Research Paper

Abstract :Cu insert ignore into journalissuearticles values(II); phthalocyanine compound and its water-soluble derivative containing 3- insert ignore into journalissuearticles values(pyridin-4-yl); propane-1-oxy groups in non-peripheral positions were synthesized for the first time and their structures were elucidated. The photocatalytic properties of Cu insert ignore into journalissuearticles values(II); phthalocyanine compounds, which were synthesized and characterized, were investigated on the photocatalytic degradation reactions of 4-nitrophenol, one of the important environmental pollutants. In the photocatalysis reactions that took place in the photoreactor for 2 hours without using any oxidant, 4-nitrophenol compound was completed with 94.4% and 98.6% conversion to toxic and non-harmful species. The hydroquinone compound was identified as the main product and the benzoquinone compound as the by-product. The conversion number for the non-peripheral Cu insert ignore into journalissuearticles values(II); phthalocyanine compound and its water-soluble derivative was 471 and 488 and the conversion frequency was 235.5 and 244,0 respectively. Finally, recovery studies were carried out for water soluble Cu insert ignore into journalissuearticles values(II); phthalocyanine used as photocatalyst and the number of cycles was determined as 5.
Keywords : Non peripheral, Phthalocyanine, Copper, Photocatalytic, 4 Nitrophenol