The synthesis of polymeric s-Triazine schiff bases and investigation of [(Fe(III)/Mn(III)(Salen)Cl] metal complexes

Authors : Nihal Yildirim, Ziya Erdem Koç

Pages : 29-36

Doi:10.35238/sufefd.1282991

View : 102 | Download : 107

Publication Date : 2023-10-30

Article Type : Research Paper

Abstract :In this study, 2,4,6-triamino-1,3,5-triazine (melamine) as the starting material. A one-way Schiff base reaction took place with the condensation reaction of melamine and p-hydroxybenzaldehyde. Then, monopodal s-triazine-centered Schiff base ligand complexes were obtained by obtaining a single oxygen-bridged compound of [(Fe(III)/Mn(III)Salen)Cl] ligand complexes, which we synthesized monopodal Schiff base s-triazine monomer by the literature. The obtained unidirectional s-triazine-centered Schiff base ligand complexes were polymerized under reflux with different dialdehyde compounds. Consequently, the structures of the obtained all ligands and complexes were characterized using elemental analysis, FT-IR spectroscopy, 1H-NMR spectroscopy, ESI-LS-MS spectroscopy, TGA-DTA analysis and magnetic susceptibility measurement techniques.
Keywords : melamine, Schiff baz, s triazin, salen, polimer kompleks