SYNTHESIS AND CHARACTERIZATION OF THE Td-TYPE CLATHRATES: M(2,2- DIMETHYL-1,3-DIAMINOPROPANE)M'(CN)4.2C6H6 (M= Mn or Cd, M'= Cd, Hg or Zn)

Authors : Türkay Aytekin AYDIN

Pages : 139-145

Doi:10.18038/aubtda.300421

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Publication Date : 2017-03-31

Article Type : Research Paper

Abstract :Mn(DMPDA)M(CN) 4 .2C 6 H 6 (M = Cd, Hg or Zn; DMPDA = 2,2-dimethyl-1,3-diaminopropane) and Cd(DMPDA)M(CN) 4 .C 6 H 6 (M= Cd or Hg) Hofmann-T d -type clathrates were synthesized and characterized by vibrational spectroscopy. Infrared spectra of Mn(DMPDA)M(CN) 4 .2C 6 H 6 (M = Cd, Hg or Zn; DMPDA = 2,2-dimethyl-1,3-diaminopropane), the vibrational spectra of Cd(DMPDA)M(CN) 4 .C 6 H 6 (M= Cd or Hg) were reported. All the vibrational modes of coordinated DMPDA were characterised. The spectral features suggested that these compounds were similar in structure to the Hofmann-T d -type clathrates.
Keywords : Benzene, 2, 2 Dimethyl 1, 3 diaminopropane, Hofmann Td type clathrates, Vibrational spectra