SYNTHESIS AND CHARACTERIZATION OF THE Td-TYPE CLATHRATES: M(2,2- DIMETHYL-1,3-DIAMINOPROPANE)M`(CN)4.2C6H6 (M= Mn or Cd, M`= Cd, Hg or Zn)

Authors : Türkay Aytekin AYDIN

Pages : 139-145

Doi:10.18038/aubtda.300421

View : 15 | Download : 7

Publication Date : 2017-03-31

Article Type : Research Paper

Abstract :Mninsert ignore into journalissuearticles values(DMPDA);Minsert ignore into journalissuearticles values(CN); 4 .2C 6 H 6 insert ignore into journalissuearticles values(M = Cd, Hg or Zn; DMPDA = 2,2-dimethyl-1,3-diaminopropane); and Cdinsert ignore into journalissuearticles values(DMPDA);Minsert ignore into journalissuearticles values(CN); 4 .C 6 H 6 insert ignore into journalissuearticles values(M= Cd or Hg); Hofmann-T d -type clathrates were synthesized and characterized by vibrational spectroscopy. Infrared spectra of Mninsert ignore into journalissuearticles values(DMPDA);Minsert ignore into journalissuearticles values(CN); 4 .2C 6 H 6 insert ignore into journalissuearticles values(M = Cd, Hg or Zn; DMPDA = 2,2-dimethyl-1,3-diaminopropane);, the vibrational spectra of Cdinsert ignore into journalissuearticles values(DMPDA);Minsert ignore into journalissuearticles values(CN); 4 .C 6 H 6 insert ignore into journalissuearticles values(M= Cd or Hg); were reported. All the vibrational modes of coordinated DMPDA were characterised. The spectral features suggested that these compounds were similar in structure to the Hofmann-T d -type clathrates.
Keywords : Benzene, 2, 2 Dimethyl 1, 3 diaminopropane, Hofmann Td type clathrates, Vibrational spectra