SYNTHESIS AND CHARACTERIZATION OF SOME (3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL) (METHYL) SULFANE SUBSTITUTED TITANIUM PHTHALOCYANINE DERIVATIVES

Authors : Dilek ELMALI, Gürol DEMİREL

Pages : 135-142

View : 13 | Download : 9

Publication Date : 2013-11-01

Article Type : Research Paper

Abstract :Symmetrically substituted phthalocyanine derivatives have been synthesized from the reaction of anhydrous metal salts of titanium with 4-insert ignore into journalissuearticles values(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio); phthalonitrile insert ignore into journalissuearticles values( 3); . 4-phthalonitrile insert ignore into journalissuearticles values( 1); and 4-insert ignore into journalissuearticles values(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthiol); insert ignore into journalissuearticles values( 2); in dry dimethylformamide as solvent and using K 2 CO 3 as base via the common method of nucleophilic substitution of an activated nitro group in an aromatic ring. The compound 3,9,17,23-bis[ethane-1,1- p- phenol-2,2- p- phenokxy]phthalocyaninatocobalt insert ignore into journalissuearticles values(II); insert ignore into journalissuearticles values(FlTi 2 CoPc); insert ignore into journalissuearticles values( 4); was reacted with the compound 4-insert ignore into journalissuearticles values(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio); phthalocyaninatotinanium insert ignore into journalissuearticles values(IV); insert ignore into journalissuearticles values( 5); , which is similar to those synthesized in the past, to syhthesize a new derivative containing three phthalocyanines 3,9,17,23-bis[ethane-1,1- p -insert ignore into journalissuearticles values(4-insert ignore into journalissuearticles values(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio); phthalocyaninatotinanium insert ignore into journalissuearticles values(IV););-2,2- p- phenokxy]phthalocyaninatocobalt insert ignore into journalissuearticles values(II); insert ignore into journalissuearticles values(FlTi 2 CoPc);  insert ignore into journalissuearticles values( 6); . The synthesized molecules have been characterized by 19 F NMR, HETCOR, MALDI-TOFF, UV-Vis and IR spectroscopies.
Keywords : Ftalosiyanin, Ftalonitril, MALDI TOFF