Mn and Ti Co-doping of LiNiO2 to Improve Performance

Authors : Erdinç Öz, Jeff Dahn

Pages : 280-291

Doi:10.62520/fujece.1459826

View : 76 | Download : 88

Publication Date : 2024-10-31

Article Type : Research Paper

Abstract :LiNiO2 (LNO) has high capacity but suffers from structural instability and capacity fade, which limits its practical use in lithium-ion batteries. This study proposes co-doping LNO with Mn and Ti (MnTi25) as a strategy to overcome these issues. MnTi25 was thoroughly characterized, revealing improved structural stability and significantly reduced cation mixing compared to pristine LNO. The half-cell performance of MnTi25 is noteworthy, exhibiting a capacity similar to the established 4% Mn-substituted ZoomWeMn4 standard, demonstrating efficient Li-ion extraction and insertion. Additionally, full-cell testing against a graphite anode shows that MnTi25 delivers a capacity almost identical to a commercial LNO-based material. This promising achievement highlights the effectiveness of co-doping in addressing LNO\'s limitations while preserving its high-capacity potential. This study demonstrates that MnTi25 can be a promising cathode material for high-performance lithium-ion batteries by tailoring the material\'s structure through co-doping.
Keywords : Lityum iyon bataryalar, Mn ve Ti çift katkılama, Geliştirilmiş yapısal kararlılık

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