Thermodynamic Behavior of Water from Soft-Cell Theory

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International Journal of Thermodynamics
Volume:14 Issue:1
Thermodynamic Behavior of Water from Soft-Cell Theory

Thermodynamic Behavior of Water from Soft-Cell Theory

Authors : Kuo WANG, M BREWSTER

Pages : 1-9

View : 31 | Download : 12

Publication Date : 2011-02-02

Article Type : Research Paper

Abstract :A soft-cell concept is introduced into cell theory to describe the deformable nature of water. The intermolecular vibration energy of water derived from soft-cell theory is applied to a simple energy model to explore hydrogen-bonding and associated thermodynamic properties. This study is able to accurately predict the temperature and pressure dependences of hydrogen-bonding in water and explains the distinctive thermodynamic behaviors of water in relation to hydrogen-bonding energy and intermolecular vibration energy.
Keywords : oft cell theory, cell theory, hydrogen bond, intermolecular vibration, specific heat, entropy, water

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