Error Analysis of Absolute Rate Coefficient Extrapolated Under Pseudo-First Order Conditions

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Journal of the Turkish Chemical Society Section A: Chemistry
Volume:5 Issue:1
Error Analysis of Absolute Rate Coefficient Extrapolated Under Pseudo-First Order Conditions

Error Analysis of Absolute Rate Coefficient Extrapolated Under Pseudo-First Order Conditions

Authors : Luca DOTTONE, Enunuwe OCHONOGOR

Pages : 29-40

Doi:10.18596/jotcsa.333857

View : 15 | Download : 10

Publication Date : 2017-09-01

Article Type : Research Paper

Abstract :Computer based simulations for the three-body recombination reaction of nitrogen insert ignore into journalissuearticles values(II); oxide with the hydroxyl radical have been used to estimate the error associated with the pseudo -first orderapproximation under different simulated conditions. For the absolute rate coefficients calculated by dividing the pseudo -first order constant by the concentration of the reactant in excess, the analysis of the relative error associated with working under pseudo -first order conditions shows that for a reactiants’ ratio higher than 10, the relative error is less than 5%.
Keywords : Pseudo first order conditions, absolute rate coefficient, computer simulations

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