Electrochemistry, DFT Calculations, and Antioxidant Capability of Cobalt Cefazolin Complex

Authors : Elif TURKER ACAR

Pages : 1083-1090

Doi:10.18596/jotcsa.1171945

View : 13 | Download : 8

Publication Date : 2022-11-30

Article Type : Research Paper

Abstract :The synthesis, characterization, electrochemistry, theoretical investigation and antioxidant capability of cobalt cefazolin [Coinsert ignore into journalissuearticles values(Cefaz);Cl] complex are reported here. Electrochemical characterization of the complex was carried out by using cyclic voltammetry insert ignore into journalissuearticles values(CV); and Linear Sweep Voltammetry insert ignore into journalissuearticles values(LSV); methods. Two irreversible oxidative responses and one quasi-reversible reduction couple were observed for the complex on the voltammograms. The ground state energies of the molecules have been estimated using B3LYP functional with LanL2DZ basis set based on time dependent density functional theory insert ignore into journalissuearticles values(TD-DFT);. According to the theoretical calculation, [Coinsert ignore into journalissuearticles values(Cefaz);Cl] complex can be expected to exhibit greater reactivity from Cefazolin insert ignore into journalissuearticles values(Cefaz); ligand, and the higher antioxidant properties were observed for the complex. The experimental results are in good agreement with the theoretical calculations.
Keywords : cefazolin complex, electrochemistry, DFT calculation, antioxidant capability