Metal-Free Coal Catalyst for Hydrogen Production: Synthesis and Performance Assessment

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Journal of the Turkish Chemical Society Section B: Engineering
Volume:6 Issue:2
Metal-Free Coal Catalyst for Hydrogen Production: Synthesis and Performance Assessment

Metal-Free Coal Catalyst for Hydrogen Production: Synthesis and Performance Assessment

Authors : Gurbet CANPOLAT, Mustafa KAYA

Pages : 63-72

Doi:10.58692/jotcsb.1291544

View : 46 | Download : 35

Publication Date : 2023-10-01

Article Type : Research Paper

Abstract :In this study, a coal-based catalyst produced by protonating phosphoric acid was used as a metal-free catalyst for hydrogen production from sodium borohydride insert ignore into journalissuearticles values(NaBH4); methanolysis. Experiments were conducted with various acid concentrations, impregnation times, and carbonization temperatures and times in order to produce a metal-free coal catalyst with enhanced catalytic activity. The catalyst impregnated with 3M H3PO4 for 12 h and subsequently carbonized at 600°C for 90 min exhibited the highest catalytic activity. The hydrogen production at 60 °C methanolysis with 0.25 g of NaBH4 catalyzed by a metal-free coal catalyst was found to be 11,854 mL min−1g.cat−1. Additionally, the activation energy of the catalyst was determined to be 22.5 kJ mol-1.
Keywords : Coal, Metal free catalyst, Hydrogen, phosphoric acid, Sodium Borohyride, Methanolysis

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