Photochemical Reaction of Metal Carbonyls [M(CO)6(M = Cr,Mo,W)] with 2-acetyl-5- chlorothiophenemethanesulfonylhydrazone

Authors : Sema SERT

Pages : 27-31

Doi:10.38061/idunas.463196

View : 37 | Download : 15

Publication Date : 2019-06-30

Article Type : Research Paper

Abstract :The new complexes, [Minsert ignore into journalissuearticles values(CO); 5 insert ignore into journalissuearticles values(msh4);] insert ignore into journalissuearticles values(Crinsert ignore into journalissuearticles values(1);, Moinsert ignore into journalissuearticles values(2);, Winsert ignore into journalissuearticles values(3););, have been synthesized by the photochemical reaction of metal carbonyls with 2-acetyl-5-chlorothiophenemethanesulfonylhydrazoneinsert ignore into journalissuearticles values( msh4 ); .The structure of these complexes has been investigated by using elemental analyses; FT-IR; EI-MS and 1 H NMR spectrometric methods. According to all spectroscopic data, msh4 is monodaentate and coordinate via thiophene ring sulfur.
Keywords : Metal carbonyls, Methanesulfonylhydrazone, Photochemical Reactions

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