Synthesis and aggregation properties of 2,9,16,23–tetrakis(chloro)-3,10,17,24–tetrakis[2-(4-allyl-2methoxyphenoxy)ethoxy]phthalocyaninato cobalt(II), manganese(III), zinc(II)

Authors : Gülpınar SARKI, Halise YALAZAN, Halit KANTEKİN

Pages : 75-80

Doi:10.51435/turkjac.813227

View : 15 | Download : 6

Publication Date : 2020-12-29

Article Type : Research Paper

Abstract :The synthesis of original, symmetrical cobalt, manganese and zinc phthalocyanines including eight 2-insert ignore into journalissuearticles values(4-allyl-2-methoxyphenoxy);ethanol moieties were realized by cyclotetramerization of 4,5-bisinsert ignore into journalissuearticles values(2-insert ignore into journalissuearticles values(4-allyl-2-methoxyphenoxy);ethoxy);phthalonitrile with suitable metal salts. Novel compounds having eugenol moieties were characterized by spectroscopic techniques such as FT-IR, UV-vis, 1H NMR, 13C NMR and mass spectra. Within the scope of this study, solutions peripheral octa-substituted cobalt insert ignore into journalissuearticles values(II);, manganese insert ignore into journalissuearticles values(III); and zinc insert ignore into journalissuearticles values(II); phthalocyanine compounds were prepared in different solvents and concentrations. Then, UV-vis spectra were examined to investigate the effect of solvent and concentration on aggregation.
Keywords : Phthalocyanines, Eugenol, Aggregation