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  • Turkish Journal of Analytical Chemistry
  • Volume:3 Issue:2
  • Investigation of acidic properties of 2-ethoxy-6-(3-substitue-4,5-dihydro-1H-1,2,4-triazol-5-one-4-y...

Investigation of acidic properties of 2-ethoxy-6-(3-substitue-4,5-dihydro-1H-1,2,4-triazol-5-one-4-yl-azomethine)-phenyl benzoates

Authors : Haydar YÜKSEK, Faruk KARDAŞ, Sevda MANAP, Gül ÖZDEMİR
Pages : 39-44
Doi:10.51435/turkjac.940613
View : 17 | Download : 5
Publication Date : 2021-12-30
Article Type : Research Paper
Abstract :In this study, to determine the pKa values of 2-ethoxy-6-insert ignore into journalissuearticles values(3-substitue-4,5-dihydro-1H-1,2,4-triazol-5-one-4-yl-azomethine);-phenyl benzoates insert ignore into journalissuearticles values(1-9); were titrated potentiometrically with tetrabutylammonium hydroxide in four non-aqueous solvents such as isopropyl alcohol, tert-butyl alcohol, acetone and N,N-dimethylformamide insert ignore into journalissuearticles values(DMF);, and graphs were drawn for all cases. In addition, the effects of solvents and molecular structure upon acidity compounds 1-9 were also determined and discussed. The half-neutralization potential values and the corresponding pKa values were determined by half neutralization method.
Keywords : 1, 2, 4 triazole, Schiff base, acidic properties, HNP, potentiometric titrations, pKa

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