Synthesis of axially di- and peripherally tetra-(4-{[(1E)-(4-methoxyphenyl)methylene]amino}phenoxy) group substituted metallophthalocyanines and their electrochemistry

Authors : Hüseyin Baş, Zekeriya Biyiklioğlu

Pages : 137-142

Doi:10.51435/turkjac.1381022

View : 82 | Download : 61

Publication Date : 2023-12-29

Article Type : Research Paper

Abstract :In this study, the new phthalonitrile derivative, axially di- and peripherally tetra-(4-{[(1E)-(4-methoxyphenyl)methylene]amino}phenoxy) group substituted metallophthalocyanines have been synthesized and characterized. Then electrochemical measurements of axially di- and peripherally tetra-(4-{[(1E)-(4-methoxyphenyl)methylene]amino}phenoxy) group substituted metallophthalocyanines were investigated with cyclic voltammogram (CV) technique. Phthalocyanine ring based redox processes are recorded owing to the redox inactivity of the Si4+, Cu2+ central cation of NP2-Si, NP2-Cu. NP2-Mn demonstrated both metal-based and Pc ring-based reduction processes, in contrast to NP2-Si and NP2-Cu.
Keywords : Synthesis, Phthalocyanine, Silicon, Manganese, Cyclic voltammetry