THE REACTİONS OF İNDANDİONES WITH ACTIVE METHYLENE COMPOUNDS

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Communications Faculty of Sciences University Ankara Series B Chemistry and Chemical Engineering
Volume:34 Issue:01.02
THE REACTİONS OF İNDANDİONES WITH ACTIVE METHYLENE COMPOUNDS

THE REACTİONS OF İNDANDİONES WITH ACTIVE METHYLENE COMPOUNDS

Pages : 136-140

View : 29 | Download : 9

Publication Date : 1899-01-01

Article Type : Research Paper

Abstract :We have studied the reactions of 1,3-indandione insert ignore into journalissuearticles values(I);, 2-methyI-l,3-indandione insert ignore into journalissuearticles values(II); and 2,2-dimethy!-l,3-indandione insert ignore into journalissuearticles values(III); with maloncnitrile and metliyi cyanoacetate. Both, I and II, reacted with malononitrile to give several compounds. The reaction of methyi cyano¬acetate with I gave a dark, resinous material under similar conditions, while II gave mono imine of the indandione in poor yield. The reaction of III with malononitrile and methyi cyanoaceta¬te did not take place. The structure of the compounds were confirmed on the hasis of IR, UV, lHNMR and mass spectral studies
Keywords : The reaction, material, lHNMR and mass

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