Detennination of k^/kjin the Polymerization of Methyl Acrylate and the Eguation of Rate of Termination

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Communications Faculty of Sciences University Ankara Series B Chemistry and Chemical Engineering
Volume:21
Detennination of k^/kjin the Polymerization of Methyl Acrylate and the Eguation of Rate of Terminati...

Detennination of k^/kjin the Polymerization of Methyl Acrylate and the Eguation of Rate of Termination

Authors : E PULAT

Pages : 0-0

Doi:10.1501/Commub_0000000342

View : 34 | Download : 11

Publication Date : 1974-01-01

Article Type : Research Paper

Abstract :The values of k2p/kt for methyl acrylate polymerization initiated by benzöyl peroxide and azo-bis izobutyronitrile have been determined. By using Matheson’s values for kpand kt, k2p /kt has been calculated. From these results, it is seen that the eguation of rate of termination must be given without the factor 2 which is used by some poly- mer chemists.
Keywords : Detennination, Polymerization, Acrylate

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