REACTION OF ARYL CARBAMOYL ARYL HYDRAZIDOYL CHLORIDES WITH ACTIVATED MITRILE

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Communications Faculty of Sciences University Ankara Series B Chemistry and Chemical Engineering
Volume:31
REACTION OF ARYL CARBAMOYL ARYL HYDRAZIDOYL CHLORIDES WITH ACTIVATED MITRILE

REACTION OF ARYL CARBAMOYL ARYL HYDRAZIDOYL CHLORIDES WITH ACTIVATED MITRILE

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View : 29 | Download : 10

Publication Date : 1985-01-01

Article Type : Research Paper

Abstract :The carbanions of ethylcyanoacetate, cyanoacetanilide, malononitrile and cyanoacetamide react with Aryl carbamoyl aryl hydrazidoyl cblorides insert ignore into journalissuearticles values(1 a-f); in ethanol at room temperaturc tc give the corresponding substituted pyrazoles insert ignore into journalissuearticles values(3a-f, 6a-c, 7a-e and 8a);. The structural assignments have been made on the basis of elemental analysis, spectral data and the Chemical evidence fer the resulting pyrazoles. On the other hand, aminoacetonitrile was reacted with insert ignore into journalissuearticles values(1b); and 9 to give the corresponding substituted triazines insert ignore into journalissuearticles values(13b); and quinolino [1, 2-f); ] triazone derivative insert ignore into journalissuearticles values(12);. The mechanism of the different reactions wcre discussed.
Keywords : ARYL CARBAMOY, ARYL HYDRAZIDOYL, ACTIVATED MITRILE

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