Synthesis and characterization of Multi-Functional Material MoBP3O12

Authors : Gülşah ÇELİK GÜL, Figen KURTULUŞ, Halil GÜLER

Pages : 71-74

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Publication Date : 2017-09-25

Article Type : Research Paper

Abstract :New metal borophosphate compound MoBP 3 O 12 , as a potential candidate of nonlinear optical material, was obtained by hydrothermal method. The title compound was synthesized from the mixture of MoO 3 , B 2 O 3 , and (NH 4 ) 2 HPO 4 with the molar ratio 1:0.5:3, by heating at 200 °C for 3 days. The powder X-ray diffraction data was indexed in tetragonal system with the refined unit cell parameters, a = b = 5.302 (8), c = 21.538 (4) Å and Z = 1. Stoichiometric chemical analysis of molybdenum was done by inductively coupled plasma atomic emission spectroscopy (ICP-AES) and boron content was analysed by spectrophotometric azomethine H method. The indexed powder X-ray diffraction (XRD) data with POWD program, fourier transform infrared spectroscopy (FTIR) spectrum and thermal analysis of MoBP 3 O 12 are also given in the paper.
Keywords : Borophosphate compounds, Hydrothermal synthesis, X ray diffraction, Nonlinear optic materials, POWD program