Synthesis and Crystal Structure of 4,5,12,13Tetraaza-Dibenzo[b,k]Chrysene

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Celal Bayar Üniversitesi Fen Bilimleri Dergisi
Volume:11 Issue:3
Synthesis and Crystal Structure of 4,5,12,13Tetraaza-Dibenzo[b,k]Chrysene

Synthesis and Crystal Structure of 4,5,12,13Tetraaza-Dibenzo[b,k]Chrysene

Pages : 339-344

View : 19 | Download : 14

Publication Date : 2015-12-23

Article Type : Research Paper

Abstract :New synthetic methodology of fused aromatic hydrocarbons with nitrogen heterocyclic of 4,5,12,13-Tetraaza-dibenzo[b,k]chrysene( 4 ) were designed and synthesized by chemical methods. Compound 4 fully characterized by 1 H NMR, 13 C NMR, EI-mass spectral, elemental and single crystal X-ray analysis. Molecules of 4 are completely planar and form face-to-face π-stacking. Shortest distances between fused rings of π- π interactions are 3.346 Å. Compound (4) is a potential candidate for high mobility single crystal organic field effect transistors (OFET’s).
Keywords : 4, 5, 12, 13 Tetraaza dibenzo b, k chrysene, heterocyclic aromatic hydrocarbons, organic semiconductors, crystal structure

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