Synthesis and Spectroscopic Properties of Newly Tetrapyrazinoporphyrazine Containing Gadolinium(III) Acetate

Authors : Mehmet PİŞKİN, Zafer ODABAŞ, Mahmut DURMUŞ

Pages : 602-607

Doi:10.35414/akufemubid.1180731

View : 34 | Download : 31

Publication Date : 2023-06-28

Article Type : Research Paper

Abstract :A new tetrakis-insert ignore into journalissuearticles values(2-methylpyrazino);porphyrazinato gadoliniuminsert ignore into journalissuearticles values(III); acetate complex was synthesized. Elemental analysis, Fourier-Transform Infrared, Ultraviolet-visible, and fluorescence spectroscopy techniques clarified its structure. It can dissolve very well without aggregation in both Dimethyl sulfoxide and N, N-Dimethylformamide, which have high dielectric constant and high dipole moment from polar aprotic solvent type. Its aggregation property was also investigated in dimethyl sulfoxide at different concentrations, and it was determined to contain monomeric species. In addition, its fluorescence properties were investigated in Dimethyl sulfoxide and the effect of gadoliniuminsert ignore into journalissuearticles values(III); acetate metal ion as a heavy rare earth element was determined. According to the findings in this study, it may be used as an electronic and optical material and in various technological applications such as photocatalytic applications. In addition, these findings may be useful for systems that include changes in pyrazinoporphyrazine-like forms.
Keywords : Tetrapirazinoporfirazin, Gadolinyum III, asetat, Sentez, Agregasyon, Spektroskopi