- Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi
- Volume:24 Issue:4
- Synthesis and Characterization of Novel Selenium N,S-heterocyclic carbene compounds
Synthesis and Characterization of Novel Selenium N,S-heterocyclic carbene compounds
Authors : Deniz Demir Atlı
Pages : 947-954
Doi:10.35414/akufemubid.1429062
View : 58 | Download : 55
Publication Date : 2024-08-20
Article Type : Research Paper
Abstract :Two novel benzothiazolium salts, N-(4-methoxybenzyl)benzothiazolium chloride (1a) and N-(4-tert-butylbenzyl)benzothiazolium bromide (1b), were prepared by using benzothiazole and related benzyl halides. Selenourea N,S-heterocyclic-based derivatives (2a and 2b) were obtained by the reaction of the salts with selenium in the presence of KOBut base. 1H NMR, 13C NMR and elemental analysis were used for characterization of the synthesized compounds. Also, molecular weights of the selenium adducts were validated by LC-MS/MS analysis.Keywords : Benzotiyazolyum, N, S heterosiklik karben, Selenyum, Selenoüre