- Ordu Üniversitesi Bilim ve Teknoloji Dergisi
- Volume:14 Issue:1
- Stereospecific Synthesis of cis/trans-dicarbamates
Stereospecific Synthesis of cis/trans-dicarbamates
Authors : Latif Kelebekli
Pages : 94-105
Doi:10.54370/ordubtd.1360498
View : 37 | Download : 45
Publication Date : 2024-06-30
Article Type : Research Paper
Abstract :The efficient synthesis of a new class of allylic cis/trans-dicarbamates are described. Allylic diols as key intermediates of the targeted compounds were prepared in a facile way, starting from p-benzoquinone. Reaction of allylic diol compounds with p-TsNCO resulted in the formation of cis/trans-dicarbamate groups. The structure of cis/trans-dicarbamates were determined by 1H-NMR, 13C-NMR, FT-IR and elemental analysis techniques.Keywords : stereospesifik, bis karbamatlar, trans karbamat, cis karbamat