Synthesis of Imino Stabilized Iron Oxide Nanosensor for Selective Detection of Lead Ions

Authors : Erum HASAN, Syed ALI, Ambreen ZİA, Sabira BEGUM, Salman Tariq KHAN, Syeda BUKHARİ

Pages : 277-286

Doi:10.18596/jotcsa.1097197

View : 104 | Download : 138

Publication Date : 2023-05-31

Article Type : Research Paper

Abstract :The present work describes the successful preparation of iron oxide nanoparticles insert ignore into journalissuearticles values(NSB1); stabilized with 4-insert ignore into journalissuearticles values(insert ignore into journalissuearticles values(2-hydroxybenzylidene);amino);benzoic acid. The characterization has been achieved through ultraviolet visible insert ignore into journalissuearticles values(UV-Vis);, fourier transform infra-red insert ignore into journalissuearticles values(FTIR); spectroscopy and scanning electron microscopy insert ignore into journalissuearticles values(SEM); with electron dispersive X-ray elemental analysis insert ignore into journalissuearticles values(EDX);. These magnetic nanoparticles have exhibited significant chemosensing properties in the aqueous media to screen Cr3+, Cd2+, Li+, Co2+, Al3+, Pb2+, Ni2+ and Sr2+ ions. However, lead insert ignore into journalissuearticles values(Pb2+); ions have shown the highest selectivity as compared to other metal ions without any interference in the competitive ion study. The detection limit of Pb2+ ions was found to be 1.7 µM by this nanosensor. The binding ratio and stoichiometry was found to be 1:1 as measured by Job’s plot. The binding strength was also computed through Benesei-Hildebrand equation.
Keywords : iron oxide nanoparticles, p aminobenzoic acid, Jobs plot, Chemosensors, Schiff base, Lead ions detection

ORIGINAL ARTICLE URL