Synthesis and Characterization of Metal Carbonyls [M(CO)6(M = Cr,Mo,W)] with Indole -3-carboxyaldehydemethanesulfonylhydrazone

Authors : Sema SERT

Pages : 31-34

Doi:10.38061/idunas.444281

View : 32 | Download : 12

Publication Date : 2018-12-29

Article Type : Research Paper

Abstract :Abstract Four new complexes, Minsert ignore into journalissuearticles values(CO); 5 insert ignore into journalissuearticles values(inmsh); insert ignore into journalissuearticles values(M=Crinsert ignore into journalissuearticles values(1);, Moinsert ignore into journalissuearticles values(2);,Winsert ignore into journalissuearticles values(3);); and Reinsert ignore into journalissuearticles values(CO); 4 Brinsert ignore into journalissuearticles values(inmsh); insert ignore into journalissuearticles values(4);, were synthesized by the photochemical reaction of metal carbonyls with indole-3-carboxyaldehydemethanesulfonyl hydrazoneinsert ignore into journalissuearticles values(inmsh); and characterized by using elemental analysis, 1 H NMR, LC-MS and IR spectra. The spectroscopic studies show that inmsh behaves as a monodantate ligand coordinating via imine N donor atom in [Minsert ignore into journalissuearticles values(CO); 5 insert ignore into journalissuearticles values(inmsh);] insert ignore into journalissuearticles values(M=Cr, Mo, W); and Reinsert ignore into journalissuearticles values(CO); 4 Brinsert ignore into journalissuearticles values(inmsh);.
Keywords : Sulfonylhydrazones, Metal Carbonyls

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