Infrared spectra of hofmann-Td type host complexes: Cd( pyridine )2 Cd(CN)4 and Cd(pyridine)2 Hg(CN)4

Authors : Ziya KANTARCI

Pages : 0-0

Doi:10.1501/commua1-2_0000000073

View : 37 | Download : 9

Publication Date : 1988-01-01

Article Type : Research Paper

Abstract :Two new Hofmann- Td -type camplexes of the form Cd insert ignore into journalissuearticles values(11); insert ignore into journalissuearticles values(Pyridine);2 Minsert ignore into journalissuearticles values(ll); insert ignore into journalissuearticles values(CN);4 insert ignore into journalissuearticles values(M - Cd or Hg); have been prepared and their infrared spectra are reported. Spectral data indicate that the structure of the complexes consists of hoşt framework formed from tetrahedral Minsert ignore into journalissuearticles values(CN);4 ions bridged by Cdinsert ignore into journalissuearticles values(Pyridine);2 cations so that the Cd is octahedrally surrounded by six N atoms, four from CN groups in a plane and two from the pyridine molecules.
Keywords : Infrared, complexes, Hg CN, 4

ORIGINAL ARTICLE URL