STOBBE CONDENSATION INVOLVING DIETHYL-p,^-DIMETHYL- GLUTARATE II

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Communications Faculty of Sciences University Ankara Series B Chemistry and Chemical Engineering
Volume:35
STOBBE CONDENSATION INVOLVING DIETHYL-p,^-DIMETHYL- GLUTARATE II

STOBBE CONDENSATION INVOLVING DIETHYL-p,^-DIMETHYL- GLUTARATE II

Pages : 0-0

View : 59 | Download : 7

Publication Date : 1989-01-01

Article Type : Research Paper

Abstract :Diethy]-Ş,3-dimethylglutarate condenses with furan-2-aldehyde and thiophene-2-aI- dehyde in presence of sodium hydride to give predominantly the insert ignore into journalissuearticles values(Z);-half ester insert ignore into journalissuearticles values(la,b); together with small amounts of the insert ignore into journalissuearticles values(E);-half eseter insert ignore into journalissuearticles values(2a,b);. The structure of the insert ignore into journalissuearticles values(E);-half esters was based on thier cyclization to cyclopenteno-furan and cyclopenteno-thiophene derivatives insert ignore into journalissuearticles values(5a,b); res- pectively, as well as, spectroscopic evidence.
Keywords : STOBBE CONDENSATION, INVOLVING, GLUTARATE

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