SOME KINETIC PARAMETERS ON THE CATİONİC POLY- MERIZATION OF a-METYLSTRENE (IH)

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Communications Faculty of Sciences University Ankara Series B Chemistry and Chemical Engineering
Volume:32 Issue:01.02
SOME KINETIC PARAMETERS ON THE CATİONİC POLY- MERIZATION OF a-METYLSTRENE (IH)

SOME KINETIC PARAMETERS ON THE CATİONİC POLY- MERIZATION OF a-METYLSTRENE (IH)

Pages : 34-39

View : 32 | Download : 14

Publication Date : 1986-01-01

Article Type : Research Paper

Abstract :H2SO4 initiated cationic polymerization of a - methylstyrene was carried out in chloro- jorm. The effect of temperature and monomer concentration on rate of polymerization and on the molecular weight of poly a-methylstyrene were studied. The total activation energy of the reaction was found to be - 32.6 kj mol-1, Also assuming that the transfer reactions were negligeble, it was obtained that kp/ kt was equal to 2.64xl02.
Keywords : H2SO4 initiated cationic, The effect of temperature, Also assuming

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