Adducts Of Diphenyltin Dichloride With Some Organic Donors

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Communications Faculty of Sciences University Ankara Series B Chemistry and Chemical Engineering
Volume:26
Adducts Of Diphenyltin Dichloride With Some Organic Donors

Adducts Of Diphenyltin Dichloride With Some Organic Donors

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Publication Date : 1980-01-01

Article Type : Research Paper

Abstract :Diphenyltin dichloride forms 1:1 adducts with o-pbenanthroline, 2,9-dimethylp- henanthroline, 2,2’-bipyridy‘l, 4,4’-dimethyl bipyridyl, 2,2’, 2”-tripyridyl pyridine-N- oxide, triphenylphosphine oxide, methyltri-phenylphosphonium chloride, diphenylphosp- hino ethane, -methane oxides and thianthrene-5-oxide. But it forms 2:1 adduct with diphenylphosphino ethane which on oxidation gives tbe corresponding oxide. This may be attributed to steric hindrance. Some physical studies for these adducts are reported. These incinde infrared spectra, conductivity and molecular weight determinations.
Keywords : Adducts, Diphenyltin, Organic

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