Interaction of Thorium Tetrachloride With Nitrogen and Oxygen Organic Donors

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Communications Faculty of Sciences University Ankara Series B Chemistry and Chemical Engineering
Volume:27
Interaction of Thorium Tetrachloride With Nitrogen and Oxygen Organic Donors

Interaction of Thorium Tetrachloride With Nitrogen and Oxygen Organic Donors

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Publication Date : 1981-01-01

Article Type : Research Paper

Abstract :Thorium tetrachloride reacts with organic compounds containing nitrogen or oxygen atom, to give cpmplex compounds of the type ThClj, nL, where n = 1, 1.5 or 2 and L = Djphenylp- hosphino ethane dioxide, diphenylphosphino mpthane dioxide, dimethyl-o-phenanthrolme, bipyridyl, dimethyl-bipyridyl, tripyridyl, pyridine N-oxide, dipyridyl amine and picolinic acid. Some öf these complexes contain coordinated water moleculeş. The reaction with triethyl phosp- hate gave the complex, Th insert ignore into journalissuearticles values(insert ignore into journalissuearticles values(EtO);2P02);4. 1 -No adducts have been obtained from the reaction of thorium tetrachloride with some or¬ganic phosphorus ligands. Infrâred spectra, thermal stability and conductivity of the formed coınplexes are discussed.
Keywords : Interaction, Thorium Tetrachloride, Nitrogen

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