Effect of Solvent on the Reaction Rat e. Part. III Role of Macrocyclic Ethers on the Sjy2 Reactions in Water-Dioxane Solutions

Authors : H YETİŞLİ

Pages : 0-0

Doi:10.1501/Commub_0000000133

View : 25 | Download : 9

Publication Date : 1981-01-01

Article Type : Research Paper

Abstract :Effect of some macrocyclic ethers have been investigated in the reaction of di or tri nitro phenoxides with some alkil halides in water-dioxane mixtures. Ithas been found that in most cases heptaoxa oligomer has more influence although the fact that the such compounds are more pronounced on the S]yl type of reaetions with respect to Sjy2 reaetions so that the ehters seem to capable to bind the carbonium intermediates even in water-dioxane mixtures.
Keywords : Reaction Rat, Macrocyclic Ethers, Sjy2 Reactions

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