2,4,6-Tris(p-aminoanilino)-1,3,5-triazine: Synthesis and Electron Paramagnetic Resonance (EPR) Analysis

Authors : Özgül KARATAŞ, Yusuf CEYLAN, Ziya Erdem KOÇ

Pages : 1170-1179

Doi:10.16984/saufenbilder.1135112

View : 19 | Download : 11

Publication Date : 2022-12-31

Article Type : Research Paper

Abstract :A significant group of compounds arise from substituted s-triazine derivatives that have tripodal heterocyclic compound. Compounds classified as heterocyclic possible created the largest and most diverse family of organic compounds. In this study, we reported that a new template has been syntheses from a cyanuric chloride and its diamine derivative. The desired triamine a tripodal 2, 4, 6-tris insert ignore into journalissuearticles values(p-aminoaanilino);-1, 3, 5-triazine insert ignore into journalissuearticles values(C21H21N9);, called to be TRIPOD, has been obtained from cyanuric chloride with 3 eq of p-phenylenediamine reaction in acetone. After synthesis, TRIPOD sample which was polycrystal form was irradiated by cobalt-gamma source. The electron paramagnetic resonance spectra of TRIPOD were recorded using X-band EPR spectrometer at room temperature in three axes insert ignore into journalissuearticles values(x, y, z); which are perpendicular at 10 intervals. The EPR spectrum was simulated using computer program and by using the spectrum. The radical structure was determined in the sample.
Keywords : EPR, Irradiation Effects, Radical, s Triazine, Synthesis