SYNTHESIS, CHARACTERIZATION, SPECTRAL, AGGREGATION AND FLUORESCENCE AND IMPROVED PHOTOPHYSICAL PROPERTIES OF (ethylsulfanyl) PORPHYRAZINES CONTAINING β-THIOETHER APPENDED [(bpy)2RuCl2]

Authors : Fatma Aytan KILIÇARSLAN, Ali ERDOĞMUŞ, Sabiha MANAV YALÇIN, Ahmet GÜL

Pages : 487-499

View : 39 | Download : 9

Publication Date : 2018-06-01

Article Type : Research Paper

Abstract :In this study, insert ignore into journalissuearticles values(ethylsulfanyl); porphyrazines have been modified with one peripheral ruthenium bipyridine groups. These compounds possess insert ignore into journalissuearticles values(bpy);2RuII moieties directly attached to the β position in the insert ignore into journalissuearticles values(ethylsulfanyl); porphyrazines through thioether chelation. The new compounds have been characterized by elemental analysis, FT-IR, 1H-NMR spectroscopy and mass spectra. The spectral properties such as electronic spectra, aggregation and fluorescence of compounds have been studied in THF. Insertion of insert ignore into journalissuearticles values(bpy);2RuII moiety on the porphyrazines structure have been investigated photophysical properties of the complexes.
Keywords : Porphyrazines, bipyridine, ruthenium, fluorescence, photophysics

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