Utilization of Trapa natans

Authors : Esra CEYLAN, Ayben KILIÇ PEKGÖZLÜ

Pages : 688-694

Doi:10.35229/jaes.645341

View : 48 | Download : 11

Publication Date : 2019-12-31

Article Type : Research Paper

Abstract :In this study, Trapa natans nut collected from the costs of Inkumu-Bartin was analyzed according to its lignin content. Acid-insoluble lignin content was determined according to TAPPI T222om-02 as 28.31%. TGA and FTIR analyses were performed. FTIR analysis indicated that Trapa natans contained cellulose, hemicelluloses and lignin. The peaks at 1506-1510 cm -1 in both samples are characteristic peaks for the lignin components due to C = O and COO-non-symmetric stretching vibrations in the aromatic rings of the lignin structure. 1510 cm -s peak is found in the literature as lignin’s fingerprint peak.  The peaks at 1230-1270 cm -1 band show the vibrations of guayasil ring with CO tension in lignin and hemicelluloses. Around the peaks of 900, 1025, 1030 and 1050 cm -1 bands cellulose’s O-H, C-H and C-O-C type bonds are seen. When TGA analyzes are examined, approximately 4.5% of the sample is lost from 30 °C to 200 °C. At these intervals, samples generally lose volatile constituents and moisture. From 200 to 271 °C 4.6% of the weight is lost. The decrease in this range may be due to the decomposition of cellulose and hemicelluloses. The DTG curve shows maxima weight-loss occurring at 349 °C. The weight-loss in the range from 271-352 °C is about 50%. Pure lignin sample’s TGA and DTG curve results show 10%, 50%, and 70% weight-losses at 233 °C, 489 °C, and 1167 °C respectively. According to these results, dominantly lignin and small quantities of cellulose and hemicelluloses are present in trapa samples. 
Keywords : Lignin, Trapa natans, water chesnut

ORIGINAL ARTICLE URL