A comparative investigation for identification of N-(4-dimethylamino 3,5-dinitrophenyl)maleimide

Authors : Seda KARABOĞA, Gürcan YILDIRIM

Pages : 27-46

Doi:10.54187/jnrs.1241130

View : 24 | Download : 8

Publication Date : 2023-04-30

Article Type : Research Paper

Abstract :This study has identified the characteristic behaviors of N-insert ignore into journalissuearticles values(4-dimethylamino 3,5-dinitrophenyl);maleimide molecule using ab initio Hartree-Fock insert ignore into journalissuearticles values(HF); and density functional theory insert ignore into journalissuearticles values(DFT); based on Becke’s three-parameter hybrid exchange functional combined with Lee-Yang-Parr non-local correlation function insert ignore into journalissuearticles values(HF/B3LYP and DFT/B3LYP); at 6-311G++insert ignore into journalissuearticles values(d,p); level of theory for the first time. On this basis, the optimized molecular structures, some thermodynamic features at 300 K, function groups of structures, charge distributions-dipole moments, molecular charge transfer regions, spectroscopic characteristic properties, vibrational frequencies, nuclear magnetic resonance chemical shifts of 13C-NMR and 1H-NMR spectra, and corresponding vibrational assignments have been investigated in detail. Comparisons between some experimental findings and theoretical results are performed to test the reliability of the calculation method preferred in the study. The comparison results in high correlation parameters such as R2 =0.976 and R2 =0.985 for the molecular structures and vibrational frequencies in the DFT and HF calculation levels, respectively. Moreover, the obtained vibrational frequencies and calculated results are in good agreement with the experimental data. Additionally, the simulations of highest/lowest occupied/unoccupied molecular orbital insert ignore into journalissuearticles values(HOMO and LUMO);, molecular electrostatic potential insert ignore into journalissuearticles values(MEP);, and electrostatic potential insert ignore into journalissuearticles values(ESP); maps have shown that there appear strong non-uniform intra-molecular charge distributions insert ignore into journalissuearticles values(ICT);, electron engagements, lone pairs of electrons, π-π* conjugative effects based on the bond weakening, and intermolecular hydrogen bonding in the compound. Correspondingly, the molecule with the electrophilic reactive and nucleophilic regions has been noted to exhibit kinetical chemical stability. All the discussions have been confirmed by means of the findings of optimized molecular structures and vibrational frequencies belonging to the molecule.
Keywords : N 4 dimethylamino 3, 5 dinitrophenyl, maleimide, DFT HF calculations, HOMO and LUMO, MEP, Molecular structure