Synthesis of novel tetraoxime derivative with hydrazone side groups and its metal complexes

Authors : İlknur BABAHAN, Hüseyin ANIL, Nursabah SARIKAVAKLI

Pages : 613-624

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Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :In this study, the synthesis of a novel tetraoxime insert ignore into journalissuearticles values(LH4); derivative containing hydrazone side groups, and its transition metal complexes with Niinsert ignore into journalissuearticles values(II);, Cuinsert ignore into journalissuearticles values(II);, Coinsert ignore into journalissuearticles values(II);, and Zninsert ignore into journalissuearticles values(II); ions, were reported. The ligand was synthesized by reacting anti-glyoximehydrazine insert ignore into journalissuearticles values(GH2); with terephthaldialdehyde. Polymeric complexes with Niinsert ignore into journalissuearticles values(II); and Coinsert ignore into journalissuearticles values(II); and binuclear complexes with Cuinsert ignore into journalissuearticles values(II); and Zninsert ignore into journalissuearticles values(II); of this tetraoxime were isolated. Structural assignments were supported by a combination of 1H-NMR, 13C-NMR, HMQC, FT-IR, UV-Vis, thermogravimetric analysis insert ignore into journalissuearticles values(TGA);, molar conductances, elemental analyses, and magnetic susceptibility.
Keywords : Tetraoximes, hydrazone, transition metal complexes