Spectroscopic and Structural Study of Ni(II) Dipicolinate Complex with 2-amino-4-methylpyrimidine

Authors : İclal BULUT, İbrahim UÇAR and Canan KAZAK

Pages : 347-354

Doi:10.3906/sag-1202-88

View : 14 | Download : 8

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :Nickelinsert ignore into journalissuearticles values(II); dipicolinate complex containing 2-amino-4- methylpyrimidine insert ignore into journalissuearticles values(2A-4Mpy);, [Niinsert ignore into journalissuearticles values(2A-4Mpy);insert ignore into journalissuearticles values(dpc); insert ignore into journalissuearticles values(H2O);2] . 2H2O was synthesized in solid state and its structural and spectroscopic properties were determined by XRD, IR, and UV-Vis techniques. The crystal data revealed that the Ni complex is in triclinic crystal systems with space group P-1 and Z = 2. The Niinsert ignore into journalissuearticles values(II); ion is bonded to dipicolinate ligand through pyridine N atom together with one O atom of each carboxylate group, 2 aqua ligands, and the N atom of 2-amino-4-methylpyrimidine, forming distorted octahedral geometry. IR and UV-Vis spectra of the complexes all agree with the observed crystal structure.
Keywords : Metal II, dipicolinate complexes, X ray crystal structure, UV Vis, IR