Deactivation of a Co-Precipitated Co/Al2O3 Catalyst

Authors : Meltem YILDIZ, Ayşe Nilgün AKIN

Pages : 515-521

View : 17 | Download : 7

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :The effects of reaction temperature, feed ratio, space time, and CO percentage in feed on the deactivation conditions of a co-precipitated 36 wt% Co/Al2O3 catalyst in CO hydrogenation were investigated. Environmental-SEM-EDX and temperature-programmed reduction insert ignore into journalissuearticles values(TPR); studies were performed on used catalysts to investigate the effect of reaction conditions on catalyst deactivation. Intensive coke deposition on the catalyst was observed at a reaction temperature of about 573 K. Increasing the H2/CO ratio also increased the catalyst activity. Methane formed as the main product at high H2/CO ratios. Although catalyst activity did not change significantly during the 9-h reaction period at all conditions, a maximum of 6.8% C deposition was observed with increasing H2/CO, and this caused a 2% decrease in the total surface area of the used catalyst. Space time and CO percentage in the feed had less influence on catalyst decomposition.
Keywords : Fischer Tropsch synthesis, catalyst deactivation, cobalt alumina catalysts, CO hydrogenation, co precipitation