Preparation, Spectroscopy, Antimicrobial Assay, and X-Ray Structure of Dimethyl bis-(4-methylpiperidine dithiocarbamato-S,S`)-tin(IV)

Authors : Saira SHAHZADI, Saqib ALI and GuoXin JIN

Pages : 435-442

View : 16 | Download : 8

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :Dimethyl bisinsert ignore into journalissuearticles values(4-methylpiperidine dithiocarbamato-S,S`);-tininsert ignore into journalissuearticles values(IV); was synthesized and characterized by elemental analysis, IR and mass spectrometry, multinuclear NMR insert ignore into journalissuearticles values(1H- and 13C-NMR);, and X-ray single crystal analysis. IR data showed that the ligand acts as a bidentate in the solid state. X-ray data showed the unsymmetrical nature of the ligand towards coordination to tin. It crystallized in the monoclinic P21/n space group. Its geometry is distorted octahedral. Antimicrobial activity data shows that the complex exhibits significantly more activity than the free ligand.
Keywords : Dithiocarbamate, NMR, mass, antimicrobial study, X ray structure