The Synthesis of 2-(Chloromethyl)-6-Hydroxy-2H-Pyran-3 (6H)-one via Achmatowicz Rearrangement

Authors : Zuhal GERÇEK

Pages : 491-494

View : 15 | Download : 7

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :Achmatowicz rearrangement was carried out with 2-chloro-1-insert ignore into journalissuearticles values(furan-2-yl); ethanol, which was synthesized starting from 1-insert ignore into journalissuearticles values(furan-2-yl); ethanone. It was shown that the oxidation of 2-chloro-1-insert ignore into journalissuearticles values(furan-2-yl); ethanol with m-CPBA produced 2-insert ignore into journalissuearticles values(chloromethyl);-6-hydroxy-2H-pyran-3 insert ignore into journalissuearticles values(6H);-one in good yield insert ignore into journalissuearticles values(70%);.
Keywords : Oxidation, furan, 2 chloro 1 furan 2 yl, ethanol, m CPBA, rearrangement, pyranones