Electrochemical Copolymerization of Thiophene Containing Pseudo-Polyether Cages with Pyrrole

Authors : Atilla CİHANER, Ahmet M ÖNAL

Pages : 629-634

View : 19 | Download : 8

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :Conducting copolymers were synthesized via the electrochemical oxidation of pyrrole insert ignore into journalissuearticles values(Py); in the presence of the monomer 1,12-bisinsert ignore into journalissuearticles values(2-thienyl);-2,5,8,11-tetraoxadodecane insert ignore into journalissuearticles values(I);. The presence of monomer I in the electrolytic solution greatly changed the CV behavior of Py during its potensiodynamic polymerization. The electroactivity of polyinsert ignore into journalissuearticles values(I-co-Py); increased with the increasing amount of I in the comonomer mixture. Copolymer films were prepared via constant potential electrolysis in an electrolytic solution containing 0.1 M tetrabutylammonium hexafluorophosphate insert ignore into journalissuearticles values(TBAPF6); dissolved in acetonitrile. The spectroelectrochemical properties of the films were investigated using UV-VIS spectroscopy.
Keywords : Electrochemical polymerization, spectroelectrochemistry, polymer containing pseudo polyether cages