The Crystal and Molecular Structure of New Hydrogen Dinitrate of Nitrato(2,2`,2``-terpyridyl)platinum(II) Ion, [Pt(terpy)ONO2][H(ONO2)2]

Authors : Crystal Structure Of NİTRATO

Pages : 571-578

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Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :The title compound, C15H12N6O9Pt, consists of [Ptinsert ignore into journalissuearticles values(terpy);ONO2]+ cation and [Hinsert ignore into journalissuearticles values(ONO2);2]- anion, in which 2 nitrate groups are linked by a strong hydrogen bond [O \cdots O 2449insert ignore into journalissuearticles values(1); Å]. In the cation, the terpyridine is coordinated to Pt as a tridentate ligand and the fourth position is occupied by the nitrate ion`s oxygen. The coordination around Pt is square-planar. The coordinated nitrate moiety adopts a distorted trigonal-planar configuration. It belongs to the space group P \bar{1} with a = 8.605insert ignore into journalissuearticles values(2);, b = 10.220insert ignore into journalissuearticles values(3); Å, c = 10.517insert ignore into journalissuearticles values(2); Å and a = 89.51insert ignore into journalissuearticles values(1);, b = 82.78insert ignore into journalissuearticles values(2);, g = 76.90insert ignore into journalissuearticles values(2);°.
Keywords : X ray structure, terpyridine, hydrogen, nitrate, platinum, complex