Crystal Structure of the cis-bis[4-chloro-N-(pyrrolidine-1-carbothioyl)-benzamido] copper(II) Complex

Authors : Nevzat KÜLCÜ, Ulrich FLÖRKE, Hakan ARSLAN

Pages : 1-6

View : 16 | Download : 10

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :The crystal and molecular structure of the cis-bis[4-chloro-N-insert ignore into journalissuearticles values(pyrrolidine-1-carbothioyl);-benzamido] copperinsert ignore into journalissuearticles values(II); complex was determined by single-crystal X-ray diffraction. The title compound, C24H24N4O2 S2Cl2Cu, crystalizes in the triclinic space group P-1, with Z = 4 and unit cell parameters a = 8.3877insert ignore into journalissuearticles values(5); Å, b = 12.7904insert ignore into journalissuearticles values(8); Å, c = 24.160insert ignore into journalissuearticles values(2); Å, a = 95.923insert ignore into journalissuearticles values(1); °, b = 96.001insert ignore into journalissuearticles values(1); °, and g = 95.048insert ignore into journalissuearticles values(1); °. The copper atom is 4-fold coordinated by 2 S and 2 O atoms and shows a slightly distorted planar quadratic ligand arrangement.
Keywords : Thioureas, X ray structures, Benzoylthiourea complexes, Cu II, complex