Synthesis and Complex Formation of Some Novel vic-Dioxime Derivatives of Hydrazones

Authors : Nursabah SARIKAVAKLI, Gazi İREZ

Pages : 107-116

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Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :Three novel vic-dioxime compounds and their transition metal complexes were synthesized for the first time. These ligands are anti-glyoximehydrazine insert ignore into journalissuearticles values(GH2);, anti-2-pyridinealdehydeglyoxime hydrazone insert ignore into journalissuearticles values(PyGH2); and anti-2-furancarboxaldehydeglyoxime hydrazone insert ignore into journalissuearticles values(FGH2);. The synthesized anti-glyoximehydrazine was reacted with 2-pyridinealdehyde or 2-furancarboxaldehyde to obtain the PyGH2 and FGH2 ligands. Mononuclear complexes of these ligands with a metal-ligand ratio of 1:2 were prepared with Niinsert ignore into journalissuearticles values(II);, Coinsert ignore into journalissuearticles values(II); and Cuinsert ignore into journalissuearticles values(II); ions. The structures of the ligands and complexes were determined by 1H n.m.r, i.r spectroscopy and elemental analytical techniques.
Keywords : vic Dioximes, Glyoximes, Hydrazone compounds, Metal complexes