Synthesis and Structure of Systems Containing Pyramidalized and Strained Double Bond: An Investigation on the Cycloaddition Reactions of cisand trans-3,8-dicarbomethoxy-3,8-dihydroheptalene

Authors : Synthesis and Structure of Systems Conta And

Pages : 123-133

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Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :The cycloaddition reactions of cis-3,8-dicarbomethoxy-3,8-dihydroheptalene cis-2 and trans-3,8-dicarbomethoxy-3,8-dihydroheptalene trans-2 with various dienophiles such as dimethyl acetylenedicarboxylate insert ignore into journalissuearticles values(DMAD);, p-benzoquinone, maleic anhydride, tetracyanoethylene, naphtoquinone gave monoaddition products 15-23. Further addition of benzyne and dimethyl acetylenedicarboxylate to 18 resulted in the formation of the compounds syn-25 and syn-26 having pyramidalized double bonds. The addition of benzyne to 21 and the addition of dimethyl acetylenedicarboxylate to 21, 22 and 23 gave the anti configuration products anti-26, 27 and 28, respectively. X-ray structures of syn-25, syn-26 and anti-26 show the pyramidalized angles to be 16.5o, 19.9o and 8.0o, respectively.
Keywords : Turk J Chem, 25, 2001, 123 133 Turk J Chem, vol 25, iss 1