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  • Turkish Journal of Chemistry
  • Volume:24 Issue:1
  • A Study on N-Hydroxyamide Ethoxycarbonylhydrazones

A Study on N-Hydroxyamide Ethoxycarbonylhydrazones

Authors : A Aykut İKİZLER, Ahmet DEMİRBAŞ, Rıza ABBASOĞLU
Pages : 1-8
View : 13 | Download : 9
Publication Date : 0000-00-00
Article Type : Research Paper
Abstract :The structures and electronic properties of N-hydroxyamide ethoxycarbonylhydrazones were investigated by a quantum-chemical method AMl. The total energies, heats of formation, dipol moments, ionization potentials, proton affinities and energies of frontier molecular orbitals insert ignore into journalissuearticles values(EHOMO and ELUMO); were calculated and discussed. The stabilities of the tautomeric forms and of E and Z isomers for these compounds were determined. The complex forming ability of these compounds with metal cations was also studied. The geometry and electronic properties of the complexes formed by N-hydroxyacetamide ethoxycarbonylhydrazone with Ni2+ and Cu2+ were investigated using ZINDO/1 semiempirical method. Moreover, these complexes were synthesized and identified.
Keywords : Turk J Chem, 24, 2000, 1 8 Turk J Chem, vol 24, iss 1

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