A study of the thermodynamic properties of poly [2-(3-mesityl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate] at infinite dilution using inverse gas chromatography-2-hydroxyethyl

Authors : İsmet KAYA

Pages : 171-180

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Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :Some thermodynamic quantities were obtained for the interactions of poly [2-insert ignore into journalissuearticles values(3-mesityl-3-methylcyclobutyl);-2-hydroxyethyl methacrylate] with alcohols, ketones, acetates, aromatics and alkanes by inverse gas chromatography in the temperature range 160-200°C. The specific retention volumes, V°g, weight fraction activity coefficients of solute probes at infinite dilution, W\infty1, Flory-Huggins thermodynamic interaction parameters, c\infty12 between polymer and solvents were determined. The partial molar free energy, D \bar{G}\infty1, the partial molar heat of mixing, D\bar{H}\infty1 at infinite dilution and the solubility parameters of the polymer, d2 were calculated.
Keywords : Poly 2 3 mesityl 3 methylcyclobutyl, 2 hydroxyethyl methacrylate, inverse gas chromatography, polymer solvent interactions