Deposition of cadmium sulfide and zinc sulfide thin films by aerosol-assisted chemical vapors from molecular precursors

Authors : Ashfaque Ahmed MEMON, Malik DILSHAD, Neerish REVAPRASADU

Pages : 169-178

Doi:10.3906/kim-1407-37

View : 15 | Download : 9

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :New complexes with the general formula [Minsert ignore into journalissuearticles values(S2CNnBu2);2] [where M = CdII insert ignore into journalissuearticles values(1); and ZnII insert ignore into journalissuearticles values(2);] were synthesized and used as single source precursors to deposit thin films of cadmium sulfide and zinc sulfide by the aerosol-assisted chemical vapor deposition technique. The single crystal X-ray structures of 1 and 2 are also reported. Thermogravimetric analysis of 1 and 2 showed that both precursors decompose cleanly in a single step to produce their respective metal sulfides. The deposition of thin films was carried out on soda glass substrates in the 350--450 °C temperature range under inert conditions. The as-deposited thin films were characterized by powdered X-ray diffraction and field emission scanning electron microscopy. Thin films of CdS deposited at low temperature insert ignore into journalissuearticles values(350 °C); consist of densely packed granular crystallites with an average size of ca. 150 nm, while at higher temperatures insert ignore into journalissuearticles values(400 and 450 °C); particles with varying sizes and mixed morphologies are observed. The ZnS thin films deposited at 400 °C showed rod-like structures, whereas dense globular-like structures were obtained at 450 °C. Energy dispersive X-ray analysis was performed to study the chemical composition of the thin films.
Keywords : Thin films, AACVD, molecular precursor, single crystal ZnS thin films