Effect of the anchoring group in porphyrin sensitizers: phosphonate versus carboxylate linkages

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Turkish Journal of Chemistry
Volume:38 Issue:6
Effect of the anchoring group in porphyrin sensitizers: phosphonate versus carboxylate linkages

Effect of the anchoring group in porphyrin sensitizers: phosphonate versus carboxylate linkages

Authors : Christine STERN, Alla BESSMERTNYKH LEMEUNE, Yulia GORBUNOVA

Pages : 980-993

Doi:10.3906/kim-1406-42

View : 19 | Download : 9

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :Porphyrins are an important family of organic chromophores that have attracted attention as photosensitizers in TiO2-based dye-sensitized solar cells insert ignore into journalissuearticles values(DSSCs);. This brief review is dedicated to comparative studies of phosphonic and carboxylic acid anchoring groups for attachment of porphyrin sensitizers on semiconductors or conductors surface. Here we have selected some representative examples of recently described phosphonate/carboxylate porphyrins with the aim to demonstrate that porphyrin phosphonate should be a promising anchoring group for such systems.
Keywords : Phosphoryl porphyrins, carboxylate porphyrins, dye sensitized solar cells, photovoltaic performance

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