Synthesis and characterization of novel 2-{[2-(dimethylamino)ethyl](methyl)amino} ethoxy-substituted metallophthalocyanines

Authors : Hilal ZENGİN, Hacer Yasemin YENİLMEZ, Ayfer Kalkan BURAT, Zehra Altuntaş BAYIR

Pages : 1094-1101

Doi:10.3906/kim-1405-26

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Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :The synthesis of novel, symmetrical, tetrasubstituted metallophthalocyanines insert ignore into journalissuearticles values(cobalt, zinc, and copper); bearing four 2-{[2-insert ignore into journalissuearticles values(dimethylamino);ethyl]insert ignore into journalissuearticles values(methyl);amino} ethoxy units was reported. The dinitrile derivative was converted into the water-soluble quaternized product by its reaction with methyl iodide. The quaternized zinc phthalocyanine was obtained from the reaction of the water-soluble dinitrile derivative with zinc acetate. The structures of the newly synthesized molecules were proposed according to elemental analysis, 1H NMR, FT-IR, and UV-Vis spectral data.
Keywords : Phthalocyanine, 2 2 dimethylamino, ethyl methylamino ethanol, water soluble